Phosphorus Removal from Real Wastewater Using Biochar Derived from Sewage Sludge Pretreated with Zero-Valent Iron Nanoparticles in a Fixed-Bed Column

The aim of this study was to investigate the ability of sewage sludge-derived biochar to remove PO4-P from real biologically treated wastewater. Biochar was produced via the pyrolysis of anaerobically digested sewage sludge pretreated with nanoscale zero-valent iron (nZVI) at concentrations of 3%, 1.5%, and 0.5% (w/w, based on total solids). A sample without nZVI addition was used as a control. The properties of biochar samples were analyzed, including elemental composition, specific surface area, and pore size. PO4-P removal was evaluated using both batch adsorption and column experiments. The highest adsorption capacity determined in the batch experiment was 2.5 mg/g. When wastewater was passed through columns packed with 0.3–0.6 mm biochar particles at a hydraulic loading rate of 1 m/h, a 3-fold-higher phosphorus retention capacity was obtained in the range of 7.26–7.82 mg/g. The column containing biochar derived from sewage sludge with 3% nZVI accumulated 7% more PO4-P than the biochar without nZVI. All columns effectively removed phosphates from wastewater (efficiency > 80%) due to the chemical composition of biochar, which mainly contained Fe and Ca elements. In contrast to the batch experiment, the columns were subject to the biological sorption of phosphates via microorganisms, physical retention between particles, and the formation of precipitates on the surface of a column.