Two‐Dimensional Infrared Spectroscopy Reveals the Presence of a Bridging CO Ligand in Two Catalytic Intermediates of [FeFe] Hydrogenase
with a µCO ligand. The results suggest that these states are catalytically relevant intermediates with crucial implications for understanding hydrogen conversion in nature and designing new synthetic catalysts.
Authors
- Patricia Rodríguez‐Maciá (ORCID: https://orcid.org/0000-0003-3513-0115)
- Marius Horch (ORCID: https://orcid.org/0000-0001-6656-1749)
- Igor V. Sazanovich (ORCID: https://orcid.org/0000-0002-8000-7645)
- Cornelius C. M. Bernitzky
- Gregory M. Greetham (ORCID: https://orcid.org/0000-0002-1852-3403)
- James A. Birrell (ORCID: https://orcid.org/0000-0002-0939-0573)
- Manon T. Lachmann
- Mathesh Vaithiyanathan
Institutions
- University of Essex (GB)
- University of Leicester (GB)
- Research Complex at Harwell (GB)
- Freie Universität Berlin (DE)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2026-04-10
- DOI
- https://doi.org/10.1002/anie.2628759
- Primary Topic
- Metalloenzymes and iron-sulfur proteins
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Royal Society
- Royal Society of Chemistry
- Deutsche Forschungsgemeinschaft
- Einstein Stiftung Berlin