Selective π‑Metalation of Nut[6]Arene With Large and Chiral Cavity for Recognition Toward Bulky Anions in Water
to form 1:1 stable host-guest complexes. Especially, NA-3Ru-II showed strong binding abilities toward various organic sulfonate anions and carboxylate anions. Moreover, a pair of enantiomeric NA-3Ru-II was also obtained, and they exhibited enantioselective recognitions for chiral anionic guests in aqueous solution, providing a new chiral platform for anion recognition.
Authors
- Yu‐Jie Long
- Chuan‐Feng Chen (ORCID: https://orcid.org/0000-0002-4347-1406)
- Zhi‐Qiang Hu
- Xiao‐Ni Han
- Ying Han
Institutions
- Qingdao University of Science and Technology (CN)
- Beijing National Laboratory for Molecular Sciences (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2026-04-11
- DOI
- https://doi.org/10.1002/anie.8615675
- Primary Topic
- Supramolecular Chemistry and Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China