Synergistic Chirality in Spiro‐Fused Chiral Conjugated Helices
, and thus pronounced CD signals. In contrast, heterochiral configurations (P,M) produce magnetic dipoles of similar magnitude but opposite sign, resulting in near-complete cancellation and a suppressed CD response. This work provides a mechanistic understanding of stereochemical interplay in hybrid multi-chiral-centers systems and establishes a new design strategy for advanced chiroptical materials.
Authors
- Wei Jiang (ORCID: https://orcid.org/0000-0002-0153-7796)
- Xu Wen (ORCID: https://orcid.org/0000-0003-3781-1125)
- Jiangtao Chan (ORCID: https://orcid.org/0009-0007-6425-4703)
- Huajie Chen
- Zhaohui Wang
- Zelong Liu
- Zixin Liu
Institutions
- University of Chinese Academy of Sciences (CN)
- Xiangtan University (CN)
- Tsinghua University (CN)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2026-04-11
- DOI
- https://doi.org/10.1002/anie.8672298
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities