Exploring Dimethyl Carbonate as a Green and Efficient Solvent for Highly Regioselective Iodination of Arylboronic Acids

A mild and efficient method for the regioselective iodination of arylboronic acids in dimethyl carbonate is reported. Dimethyl carbonate, a well-known green solvent, promotes high regioselectivity and excellent yields, performing efficiently on both activated and nonactivated arylboronic acids, regardless of the position and nature of the substituents.

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Publication Details

Journal
ACS Omega
Published
2026-04-10
DOI
https://doi.org/10.1021/acsomega.5c13454
Citations
1
Primary Topic
Vanadium and Halogenation Chemistry
Type
article
Field-Weighted Citation Impact
7.19

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article

Exploring Dimethyl Carbonate as a Green and Efficient Solvent for Highly Regioselective Iodination of Arylboronic Acids

Francesco Ambrosio, Lucia Chiummiento, Alessandro Santarsiere, Michele Loriso
1 citations
ACS Omega
Vanadium and Halogenation Chemistry
7.19
article

Exploring Dimethyl Carbonate as a Green and Efficient Solvent for Highly Regioselective Iodination of Arylboronic Acids

Francesco Ambrosio, Lucia Chiummiento, Alessandro Santarsiere, Michele Loriso
article en
1 citations

Abstract

A mild and efficient method for the regioselective iodination of arylboronic acids in dimethyl carbonate is reported. Dimethyl carbonate, a well-known green solvent, promotes high regioselectivity and excellent yields, performing efficiently on both activated and nonactivated arylboronic acids, regardless of the position and nature of the substituents.

ACS OmegaVol. 11(15)
University of Basilicata (IT)
European Commission, NextGenerationEU
Openalex Percentile: Top 2%
Vanadium and Halogenation Chemistry
7.19
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