Synthesis and Selective Carboboration Reactivity of a Flexible P-Stabilized Bromoborenium
bond. The reaction is both chemo- and regioselective. Following the addition of XylNC, all compounds were fully characterized, including by single-crystal X-ray diffraction. DFT calculations provide mechanistic insight and reveal the key factors governing this transformation.
Authors
- Ashwini K. Phukan (ORCID: https://orcid.org/0000-0001-9286-1198)
- Ghenwa Bouhadir (ORCID: https://orcid.org/0000-0002-9061-4350)
- Mudit Jain
- Sonia Mallet-Ladeira
- Didier Bourissou
- Sreejyothi P
Institutions
- Tezpur University (IN)
- Centre National de la Recherche Scientifique (FR)
- Institut National Polytechnique de Toulouse (FR)
- Laboratoire de Chimie de Coordination (FR)
- Laboratoire Hétérochimie Fondamentale et Appliquée (FR)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-06
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c00579
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Indo-French Centre for the Promotion of Advanced Research
- Université de Toulouse
- Centre National de la Recherche Scientifique
- Science and Engineering Research Board