H···X Hydrogen Bonds Govern Chain Geometry, Thermal Expansion, and Phase Behavior in Crown-Ether-Based Lead Halide Hybrids

polyhedra and their assembly into one-dimensional inorganic chains. Consequently, the materials exhibit distinct phase-transition behaviors and pronounced anisotropic thermal expansion, including negative and near-zero thermal expansion along the chain direction. These results establish hydrogen-bond-network engineering as a general strategy for programming structural responses and thermal properties in flexible hybrid materials.

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Publication Details

Journal
Inorganic Chemistry
Published
2026-04-06
DOI
https://doi.org/10.1021/acs.inorgchem.6c00630
Primary Topic
Crystallography and molecular interactions
Type
article
Field-Weighted Citation Impact
0.00

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article

H···X Hydrogen Bonds Govern Chain Geometry, Thermal Expansion, and Phase Behavior in Crown-Ether-Based Lead Halide Hybrids

Dong-Sheng Shao, Zhengfang Tian, Jin Zhang, Gang Chen et al.
Inorganic Chemistry
Crystallography and molecular interactions
article

H···X Hydrogen Bonds Govern Chain Geometry, Thermal Expansion, and Phase Behavior in Crown-Ether-Based Lead Halide Hybrids

Dong-Sheng Shao, Zhengfang Tian, Jin Zhang, Gang Chen, Yu-Hua Mo, Xiao-Ming Ren
article en

Abstract

polyhedra and their assembly into one-dimensional inorganic chains. Consequently, the materials exhibit distinct phase-transition behaviors and pronounced anisotropic thermal expansion, including negative and near-zero thermal expansion along the chain direction. These results establish hydrogen-bond-network engineering as a general strategy for programming structural responses and thermal properties in flexible hybrid materials.

Inorganic ChemistryVol. 65(15)
Huanggang Normal University (CN), Nanjing Tech University (CN), Catalytic Materials (United States) (US), State Key Laboratory of Materials-Oriented Chemical Engineering
National Natural Science Foundation of China, Priority Academic Program Development of Jiangsu Higher Education Institutions
Openalex Percentile: Top 29%
Crystallography and molecular interactions
DOISourceOpenAlex
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