Enhancement of Oxidative Asynchronicity in Hydrogen Atom Abstraction by a Mononuclear Mn(III)-OMe Complex via Protonation and Sodium Ion Binding
to the Mn(III)-OMe complex increases the oxidative asynchronicity factor, facilitating phenolic O-H bond activation during hydrogen-atom transfer.
Authors
- Sukanta Mandal (ORCID: https://orcid.org/0000-0001-6456-3898)
- Nirmalya Podder (ORCID: https://orcid.org/0000-0002-0851-9291)
- Anannya Saha
- Suman K. Barman (ORCID: https://orcid.org/0009-0003-5336-1969)
- Mofijul Molla
Institutions
- Indian Institute of Science Education and Research Kolkata (IN)
- Indian Institute of Technology Kharagpur (IN)
- Indian Institute of Science Education and Research Mohali (IN)
- National Institute of Technology Agartala (IN)
- Indian Institute of Science Education and Research, Bhopal (IN)
- Indian Institute of Science Education and Research Berhampur (IN)
- Indian Institute of Science Education and Research, Tirupati (IN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-03
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c00033
- Primary Topic
- Metal-Catalyzed Oxygenation Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Council of Scientific and Industrial Research, India
- Indian Institute of Technology Kharagpur
- Science and Engineering Research Board