Unidentified Halon-2402 emissions in East Asia are driving the global trend

Halon-2402 (1,2‑dibromotetrafluoroethane, H-2402) is a potent ozone‑depleting substance and greenhouse gas whose global production has been banned under the Montreal Protocol since 2010, while the use of recovered or recycled stocks remains permitted for essential uses. Although these controls led to nearly two decades of declining atmospheric abundances, recent observations indicate renewed emissions. Here, we present the first observation-based regional emission estimates of H-2402 in East Asia for 2008–2023, derived using high-frequency measurements at Gosan, South Korea, and a Bayesian inversion framework. While most AGAGE stations measure background mole fractions or intermittent low-level increases, Gosan exhibits increasingly frequent and intense pollution events, revealing growing regional emissions. We find that East Asia accounted for most global H-2402 emissions in recent years, with particularly sharp increases in Japan and the Vladivostok region of Russia. Since 2015, regional emissions from East Asia have effectively driven the global emission trend, reversing the long-term decline. These emissions are spatially linked to petrochemical infrastructure, ship-repair activity, and military decommissioning sites, suggesting releases from legacy halon banks rather than new production. Cumulative emissions from East Asia between 2008 and 2023 reached ~52 Gg CFC-11-equivalent emissions. These findings imply a tangible delay in ozone layer recovery and underscore the urgent need for strengthened monitoring, transparent reporting, and verifiable management of remaining H-2402 stocks under the Montreal Protocol.

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Publication Details

Journal
npj Climate and Atmospheric Science
Published
2026-04-03
DOI
https://doi.org/10.1038/s41612-026-01399-4
Primary Topic
Atmospheric Ozone and Climate
Type
article
Field-Weighted Citation Impact
0.00

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article

Unidentified Halon-2402 emissions in East Asia are driving the global trend

Jens Mühle, Ronald G. Prinn, Haklim Choi, Isobel J. Simpson et al.
npj Climate and Atmospheric Science
Atmospheric Ozone and Climate
article

Unidentified Halon-2402 emissions in East Asia are driving the global trend

Jens Mühle, Ronald G. Prinn, Haklim Choi, Isobel J. Simpson, Jooil Kim, R. F. Weiss, ‪Sunyoung Park, Simon O’Doherty, Ben Adam, Luke M. Western, Dickon Young, Matthew Rigby, Paul B. Krummel, Anita Ganesan, Rona L. Thompson, Martin K. Vollmer
article en

Abstract

Halon-2402 (1,2‑dibromotetrafluoroethane, H-2402) is a potent ozone‑depleting substance and greenhouse gas whose global production has been banned under the Montreal Protocol since 2010, while the use of recovered or recycled stocks remains permitted for essential uses. Although these controls led to nearly two decades of declining atmospheric abundances, recent observations indicate renewed emissions. Here, we present the first observation-based regional emission estimates of H-2402 in East Asia for 2008–2023, derived using high-frequency measurements at Gosan, South Korea, and a Bayesian inversion framework. While most AGAGE stations measure background mole fractions or intermittent low-level increases, Gosan exhibits increasingly frequent and intense pollution events, revealing growing regional emissions. We find that East Asia accounted for most global H-2402 emissions in recent years, with particularly sharp increases in Japan and the Vladivostok region of Russia. Since 2015, regional emissions from East Asia have effectively driven the global emission trend, reversing the long-term decline. These emissions are spatially linked to petrochemical infrastructure, ship-repair activity, and military decommissioning sites, suggesting releases from legacy halon banks rather than new production. Cumulative emissions from East Asia between 2008 and 2023 reached ~52 Gg CFC-11-equivalent emissions. These findings imply a tangible delay in ozone layer recovery and underscore the urgent need for strengthened monitoring, transparent reporting, and verifiable management of remaining H-2402 stocks under the Montreal Protocol.

npj Climate and Atmospheric Science
CSIRO Oceans and Atmosphere (AU), Commonwealth Scientific and Industrial Research Organisation (AU), Scripps Institution of Oceanography (US), University of California, Irvine (US), Kyungpook National University (KR), University of Bristol (GB), University of California San Diego (US), Kjeller Innovasjon (Norway) (NO), Institute for Sustainability (GB), Massachusetts Institute of Technology (US), Swiss Federal Laboratories for Materials Science and Technology (CH)
National Aeronautics and Space Administration, European Commission, University of Bristol, Commonwealth Scientific and Industrial Research Organisation, Korea Meteorological Administration, National Oceanic and Atmospheric Administration, HORIZON EUROPE Framework Programme, Bundesamt für Umwelt
Industry, innovation and infrastructure
Openalex Percentile: Top 21%
Atmospheric Ozone and Climate
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