Double Fourier Sphere Methods With Low Rank Approximation for Block Copolymer Systems on Sphere

ABSTRACT We introduce Double Fourier Sphere (DFS) methods for the Ohta–Kawasaki (OK) and Nakazawa–Ohta (NO) models on a spherical domain, examining their coarsening dynamics and equilibrium pattern formations. We employed DFS for spatial discretization and the second‐order Backward Differentiation Formula (BDF2) scheme for time evolution, resulting in an efficient energy‐stable scheme to simulate the OK and NO models on the unit sphere. Our numerical experiments reveal various self‐assembled patterns, such as single‐bubble assemblies in binary systems and double‐bubble and mixed‐bubble assemblies in ternary systems. These patterns closely resemble experimental biomembrane patterns, demonstrating the effectiveness of the OK model in real‐world applications. Additionally, our study explores the relationship between repulsive strength and the number of bubbles in assemblies, confirming the two‐thirds law in the OK model. This provides quantitative evidence of how self‐assembled patterns depend on system parameters in copolymer systems.

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Publication Details

Journal
Numerical Methods for Partial Differential Equations
Published
2026-04-02
DOI
https://doi.org/10.1002/num.70091
Primary Topic
Block Copolymer Self-Assembly
Type
article
Field-Weighted Citation Impact
0.00

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article

Double Fourier Sphere Methods With Low Rank Approximation for Block Copolymer Systems on Sphere

Wangbo Luo
Numerical Methods for Partial Differential Equations
Block Copolymer Self-Assembly
article

Double Fourier Sphere Methods With Low Rank Approximation for Block Copolymer Systems on Sphere

Wangbo Luo
article en

Abstract

ABSTRACT We introduce Double Fourier Sphere (DFS) methods for the Ohta–Kawasaki (OK) and Nakazawa–Ohta (NO) models on a spherical domain, examining their coarsening dynamics and equilibrium pattern formations. We employed DFS for spatial discretization and the second‐order Backward Differentiation Formula (BDF2) scheme for time evolution, resulting in an efficient energy‐stable scheme to simulate the OK and NO models on the unit sphere. Our numerical experiments reveal various self‐assembled patterns, such as single‐bubble assemblies in binary systems and double‐bubble and mixed‐bubble assemblies in ternary systems. These patterns closely resemble experimental biomembrane patterns, demonstrating the effectiveness of the OK model in real‐world applications. Additionally, our study explores the relationship between repulsive strength and the number of bubbles in assemblies, confirming the two‐thirds law in the OK model. This provides quantitative evidence of how self‐assembled patterns depend on system parameters in copolymer systems.

Numerical Methods for Partial Differential EquationsVol. 42(3)
Hong Kong Polytechnic University (HK), George Washington University (US)
National Science Foundation, Simons Foundation
Affordable and clean energy
Openalex Percentile: Top 26%
Block Copolymer Self-Assembly
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