Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex
< 140°), whereas the less polarized diarylmethylidene analogues were found to display a more linear geometry. The geometric differences correlate with a divergent reactivity upon thermal activation. Both types of N-heterocyclic allenes can be used as carbon-donor ligands for transition metal complexes.
Authors
- Bastiaan Kooij (ORCID: https://orcid.org/0000-0003-0369-5488)
- Kay Severin (ORCID: https://orcid.org/0000-0003-2224-7234)
- Damien W. Chen
- Rosario Scopelliti
- Farzaneh Fadaei‐Tirani
Institutions
- École Polytechnique Fédérale de Lausanne (CH)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2026-04-02
- DOI
- https://doi.org/10.1002/anie.5744116
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00