Hydrogeochemistry and Accelerating Salinization of Groundwater in the Saoura Valley Oases (Southwest, Algeria)

The Saoura Valley (southwestern Algeria) hosts14 oases that primarily depend on groundwater in an endorheic basin. The hydrogeological system is bisected by the Saoura Wadi into two distinct compartments: an active, interconnected eastern compartment (Mio–Plio–Quaternary alluvial aquifer and terraces of the Great Western Erg) and a passive, fossil western compartment (Guir Hamada and Cambro–Ordovician aquifers). In September 2024, 51 groundwater samples were collected from nine oases. Temperature ranged from 16.2 to 31.4 °C and pH ranged from 7.1 to 7.85. Total dissolved solids (TDS) varied widely (179–4480 mg/L; median of 454 mg/L), with electrical conductivity between 280 and 7000 µS/cm. Three main hydrochemical facies were identified: Ca–Mg–SO4–Cl (30%), Na–Cl–SO4 (55%), and hypersaline types in the terminal inferoflux zone. Nitrate concentrations exceeded the WHO guideline (50 mg/L) in 22% of samples, attributed to localized agricultural and domestic inputs. Geochemical evolution is controlled by evaporite dissolution (gypsum, halite), cation exchange, and evaporative concentration, with a downstream salinity gradient from freshwaters near the Great Western Erg toward hypersaline inferoflux. Comparison with historical data (1941, 1963, and earlier studies) indicates a trend of increasing salinization since the 1990s, associated with intensive borehole pumping and irrigation return flow. These findings suggest risks to the long-term sustainability of the Saoura oases.