Origin of the <sup>31</sup> P NMR Chemical Shift in Lewis Acid Adducts of Triethylphosphine Oxide. Does the Gutmann–Beckett Method Relate to Lewis Acid Strength?
, to P═O bond weakening. Thus, the Gutmann-Beckett method does not provide information on adduct formation energy, the more typically sought measure of Lewis acidity, but rather provides a different thermodynamic descriptor of Lewis acid strength in the weakening of the P═O bond.
Authors
- Matthew P. Conley (ORCID: https://orcid.org/0000-0001-8593-5814)
- Alexander A. Kolganov (ORCID: https://orcid.org/0000-0002-0262-8892)
- Evgeny A. Pidko (ORCID: https://orcid.org/0000-0001-9242-9901)
- Maximillian Kling
Institutions
- University of California System (US)
- Delft University of Technology (NL)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-04-01
- DOI
- https://doi.org/10.1021/jacs.5c17621
- Citations
- 1
- Primary Topic
- Advanced NMR Techniques and Applications
- Type
- article
- Field-Weighted Citation Impact
- 9.69
Funders
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek
- Division of Chemistry