Inside Back Cover: Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis (Angew. Chem. Int. Ed. 17/2026)

Alkyne metathesis was used to selectively form conjugated triynes. Owing to the reversible cleavage and formation of carbon–carbon triple bonds, the reaction operates under thermodynamic control. The potential of this approach was demonstrated through the synthesis of triyne precursors to [7]cumulenes, a pentayne, a heptayne, and macrocycles containing triyne motifs. More in the Communication (e23344) by Rik R. Tykwinski, Matthias Tamm, Marc Mauduit, Yann Trolez, and co-workers.

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Publication Details

Journal
Angewandte Chemie International Edition
Published
2026-04-01
DOI
https://doi.org/10.1002/anie.2026-m2603124200
Primary Topic
Synthetic Organic Chemistry Methods
Type
article
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article

Inside Back Cover: Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis (Angew. Chem. Int. Ed. 17/2026)

Angelika Neitzel, Yann Trolez, Jonathan Long, Dirk Bockfeld et al.
Angewandte Chemie International Edition
Synthetic Organic Chemistry Methods
article

Inside Back Cover: Synthesis of Conjugated Linear and Cyclic Polyynes by Selective Alkyne Metathesis (Angew. Chem. Int. Ed. 17/2026)

Angelika Neitzel, Yann Trolez, Jonathan Long, Dirk Bockfeld, Mehdi Koohgard, Dylan Bouëtard, Shedrack Nwachukwu, Thierry Roisnel, Julien Escudero, Matthias Tamm, Jennifer Morvan, Marc Mauduit, Rik R. Tykwinski
article en

Abstract

Alkyne metathesis was used to selectively form conjugated triynes. Owing to the reversible cleavage and formation of carbon–carbon triple bonds, the reaction operates under thermodynamic control. The potential of this approach was demonstrated through the synthesis of triyne precursors to [7]cumulenes, a pentayne, a heptayne, and macrocycles containing triyne motifs. More in the Communication (e23344) by Rik R. Tykwinski, Matthias Tamm, Marc Mauduit, Yann Trolez, and co-workers.

Angewandte Chemie International EditionVol. 65(17)
University of Alberta (CA), École Nationale Supérieure de Chimie de Rennes (FR), Université de Rennes (FR), Technische Universität Braunschweig (DE)
Openalex Percentile: Top 26%
Synthetic Organic Chemistry Methods
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