Palladium-Catalyzed Photoredox Aminocarbonylative [3 + 2 + 1] Heteroannulation of Propargyl Acetates with α-Aminoazoles and CO
/DPEPhos]* irradiated by visible light is intercepted with propargyl acetates to generate the propargyl radicals, followed by isomerization and insertion of CO, to afford the carbonyl radicals, radical polar crossover, allene nucleophilic hydroamination, and isomerization cascades.
Authors
- Minmin Hu
- Qi Xue (ORCID: https://orcid.org/0000-0003-3418-3063)
- Hu Cai
- Yuan Li (ORCID: https://orcid.org/0000-0002-3897-9942)
- Jin-Heng Li
Institutions
- Nanchang University (CN)
- Qingdao University of Science and Technology (CN)
- Ingenierie des Materiaux polymeres (FR)
- State Key Laboratory of Applied Organic Chemistry
- Henan Normal University (CN)
- Lanzhou University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-04-01
- DOI
- https://doi.org/10.1021/acs.orglett.6c00926
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Henan Normal University
- National Natural Science Foundation of China
- Taishan Scholar Project of Shandong Province
- Jiangxi Provincial Department of Science and Technology