Traceless Silicon-Tether Strategy for the Synthesis of a Tetraphenylammonium Salt
. DFT calculations suggest β-silicon stabilization in the cyclization transition state, although competing pathways are kinetically favored. This work highlights the potential of intramolecular designs for accessing sterically hindered organic cations.
Authors
- Munetaka Kunishima (ORCID: https://orcid.org/0000-0002-3296-490X)
- Hikaru Fujita (ORCID: https://orcid.org/0000-0002-0430-9705)
- Shiori Kobayashi (ORCID: https://orcid.org/0000-0002-5513-0676)
- Yuria Sato
Institutions
- Kanazawa University (JP)
- Kobe Gakuin University (JP)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-04-01
- DOI
- https://doi.org/10.1021/acs.orglett.6c00906
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Japan Society for the Promotion of Science