Concise Synthesis of a High-Energy and Insensitive Fused [5,5,5,6]-Tetracyclic Furazan Energetic Material via Synchronous Cyclization
A fused [5,5,5,6]-tetracyclic furazan energetic compound was concisely synthesized via synchronous cyclization, which possesses a high density (1.968 g·cm–3 at 100 K, 1.914 g·cm–3 at 298 K), a good stability (IS: 40 J, FS: 192 N, Td: 262 °C) and a satisfactory energy performance (Dv: 8590 m·s–1, P: 31.0 GPa). Generally, this compound has a better stability than all the reported energetic fused [5,5,5,6]-tetracyclic compounds and an energy performance comparable to that of benzotrifuroxan (BTF).
Authors
- C. A. Liu
- Haijun Yang
- Hu Li (ORCID: https://orcid.org/0000-0002-2670-874X)
- X. F. Wang
- qianzai zhou
- Mei Zhong
- Hugen Xie
- Junfu Lai
- Ming Huang
- Hualing Cheng
Institutions
- Southwest University of Science and Technology (CN)
- Canadian Association of Emergency Physicians (CA)
Publication Details
- Journal
- Crystal Growth & Design
- Published
- 2026-03-31
- DOI
- https://doi.org/10.1021/acs.cgd.6c00213
- Primary Topic
- Energetic Materials and Combustion
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Sichuan Province