Cu-Catalyzed [1,3]-Fluorine Rearrangement Reactions of <i>N</i> -Fluoroanilines
carbon in a site-selective manner. DFT calculations suggested that the reaction proceeds via the coordination of a Cu(III) species to fluoride and aniline nitrogen, followed by C-F bond formation through a nucleophilic attack by the fluoride.
Authors
- Itaru Nakamura (ORCID: https://orcid.org/0000-0002-1452-5989)
- Takuma Sato
- Mao Suzuki
- Masahiro Terada
Institutions
- Tohoku University (JP)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-04-01
- DOI
- https://doi.org/10.1021/acs.orglett.6c01176
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Japan Society for the Promotion of Science