Expanding the Reactivity of Masked Divalent Lanthanide–Isocarbonyl Complexes
, while the dysprosium analogue exhibits slow magnetic relaxation governed by Raman and quantum tunnelling processes. These results establish isocarbonyl-bridged lanthanide metallocenes as platforms for ligand-based reduction chemistry involving metals with very limited divalent chemistry.
Authors
- S. R. Giblin (ORCID: https://orcid.org/0000-0003-1876-8619)
- Arpan Mondal (ORCID: https://orcid.org/0000-0001-9192-7255)
- Siobhan R. Temple
- Jinkui Tang
- Richard A. Layfield
Institutions
- Beijing Institute of Technology (CN)
- University of Sussex (GB)
- Cardiff University (GB)
Publication Details
- Journal
- Organometallics
- Published
- 2026-03-31
- DOI
- https://doi.org/10.1021/acs.organomet.6c00042
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- University of Sussex
- Engineering and Physical Sciences Research Council