Fluorinated Alkyl Zinc Bromides in Cu/Photoredox Promoted Decarboxylative Cross‐Coupling
The cross‐coupling of esters of N‐hydroxyphthalimide with fluorinated alkyl zinc reagents resulting in the C(sp 3 )−C(sp 3 ) bond formation is described. The method involves readily accessible perfluorinated and tetrafluorinated alkyl zinc bromides. The reaction is performed under copper and photoredox dual catalysis conditions.
Authors
- Vitalij V. Levin (ORCID: https://orcid.org/0000-0002-5606-8085)
- Alexander D. Dilman (ORCID: https://orcid.org/0000-0001-8048-7223)
- Anton A. Gladkov (ORCID: https://orcid.org/0000-0003-4235-6745)
- Sergey A. Imaev
Institutions
- Lomonosov Moscow State University (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2026-03-31
- DOI
- https://doi.org/10.1002/adsc.70389
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00