Effect of Automated Multi-Pass MAG Welding Parameters on the Fracture Toughness and Hydrogen Embrittlement Susceptibility of API 5L X70 Pipeline Steel

Welded joints in API 5L X70 pipeline steel represent critical locations for pipelines intended for hydrogen service because welding can create microstructural inhomogeneity, stress concentrations, and uneven mechanical properties that can promote hydrogen-assisted degradation. In hydrogen-containing environments, these effects may manifest as reduced ductility, loss of fracture resistance, and increased cracking susceptibility, particularly in the weld metal and heat-affected zone. Therefore, welding procedures for X70 intended for hydrogen applications must be evaluated using systematic mechanical testing and microstructural characterization under defined hydrogen exposure conditions. The study investigates the detrimental effects of hydrogen on the mechanical integrity of pipeline materials, focusing on welded joints of the API 5L X70 steel, a candidate material for use in hydrogen-containing environments. The weldability and structural performance of the X70 pipeline steel joints in hydrogen environments, produced using automated multi-pass metal active gas (MAG) welding, was experimentally studied. Welding was performed on a DN800 pipe with precise control over welding parameters. Comprehensive analyses were conducted on the welded joints, including microstructure examinations, hardness measurements, slow strain rate testing in high-pressure gaseous H2 with a N2 baseline and fracture toughness testing. In high-pressure hydrogen SSRT showed a moderate reduction in ductility relative to nitrogen, with reduction of area decreasing from 81.2% (N2) to 69.1 and 71.5% (H2), while time-to-failure remained comparable (475 min in N2 vs. 497 and 496 min in H2) Ultimate tensile strength was not reduced (579 MPa in N2 vs. 609 and 597 MPa in H2). Secondary surface cracks were observed only on specimens tested in hydrogen. Fracture mechanics testing after hydrogen exposure yielded KIH values of 58–59 MPa√m in the weld metal and 57–61 MPa√m in the HAZ, exceeding the 55 MPa√m acceptance threshold applied in this study. The results highlight the necessity of optimized welding techniques and targeted material analyses to ensure the safety and durability of pipelines in hydrogen-rich environments, thereby contributing to the development of reliable infrastructure for sustainable energy systems.

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Publication Details

Journal
Processes
Published
2026-03-27
DOI
https://doi.org/10.3390/pr14071069
Primary Topic
Hydrogen embrittlement and corrosion behaviors in metals
Type
article
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article

Effect of Automated Multi-Pass MAG Welding Parameters on the Fracture Toughness and Hydrogen Embrittlement Susceptibility of API 5L X70 Pipeline Steel

Maja Remenar, Danko Ćorić, Ivica Garašić, Kristijan Jurgec
Processes
Hydrogen embrittlement and corrosion behaviors in metals
article

Effect of Automated Multi-Pass MAG Welding Parameters on the Fracture Toughness and Hydrogen Embrittlement Susceptibility of API 5L X70 Pipeline Steel

Maja Remenar, Danko Ćorić, Ivica Garašić, Kristijan Jurgec
article en

Abstract

Welded joints in API 5L X70 pipeline steel represent critical locations for pipelines intended for hydrogen service because welding can create microstructural inhomogeneity, stress concentrations, and uneven mechanical properties that can promote hydrogen-assisted degradation. In hydrogen-containing environments, these effects may manifest as reduced ductility, loss of fracture resistance, and increased cracking susceptibility, particularly in the weld metal and heat-affected zone. Therefore, welding procedures for X70 intended for hydrogen applications must be evaluated using systematic mechanical testing and microstructural characterization under defined hydrogen exposure conditions. The study investigates the detrimental effects of hydrogen on the mechanical integrity of pipeline materials, focusing on welded joints of the API 5L X70 steel, a candidate material for use in hydrogen-containing environments. The weldability and structural performance of the X70 pipeline steel joints in hydrogen environments, produced using automated multi-pass metal active gas (MAG) welding, was experimentally studied. Welding was performed on a DN800 pipe with precise control over welding parameters. Comprehensive analyses were conducted on the welded joints, including microstructure examinations, hardness measurements, slow strain rate testing in high-pressure gaseous H2 with a N2 baseline and fracture toughness testing. In high-pressure hydrogen SSRT showed a moderate reduction in ductility relative to nitrogen, with reduction of area decreasing from 81.2% (N2) to 69.1 and 71.5% (H2), while time-to-failure remained comparable (475 min in N2 vs. 497 and 496 min in H2) Ultimate tensile strength was not reduced (579 MPa in N2 vs. 609 and 597 MPa in H2). Secondary surface cracks were observed only on specimens tested in hydrogen. Fracture mechanics testing after hydrogen exposure yielded KIH values of 58–59 MPa√m in the weld metal and 57–61 MPa√m in the HAZ, exceeding the 55 MPa√m acceptance threshold applied in this study. The results highlight the necessity of optimized welding techniques and targeted material analyses to ensure the safety and durability of pipelines in hydrogen-rich environments, thereby contributing to the development of reliable infrastructure for sustainable energy systems.

ProcessesVol. 14(7)
University of Zagreb (HR)
Openalex Percentile: Top 8%
Hydrogen embrittlement and corrosion behaviors in metals
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