Study on a Thermally Crosslinking Clay-Free Weak Gel Water-Based Drilling Fluid

In this study, a thermally crosslinking clay-free weak gel water-based drilling fluid based on salt-responsive polymers and crosslinking agents was investigated as a promising and feasible strategy. Firstly, a salt-tolerant polymer was synthesized using N,N-dimethylacrylamide (DMAA), [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfonopropyl)ammonium hydroxide (DMAPS), and acrylamide (AM). BPEI10,000 was selected as the thermal crosslinking agent. The optimal crosslinking was achieved at 180 °C and 36% NaCl, with RMFL at 2.0% and BPEI10,000 at 0.1%. Performance evaluation demonstrated that the crosslinking between RMFL and BPEI10,000 could enhance the AV, PV, and YP of the RMFL(BPEI10,000)/CF-WBDFs after aging at 180 °C for 16 h and reduce FLAPI. The RMFL(BPEI10,000)/CF-WBDFs exhibited appropriate shear-thinning behavior, viscoelasticity, thixotropy, and recoverable viscosity under high-temperature, high-salinity, and high-pressure conditions. Mechanism analysis revealed that RMFL and BPEI10,000 could form a predominantly negatively charged, three-dimensional crosslinking weak gel at high temperatures. The crosslinking weak gel could form dense filter cakes, improving rheological properties and reducing filtration loss of CFWBDFs in high-temperature, high-salinity environments. This paper proposed a novel method to address the technical challenge of rheological performance failure of CFWBDFs, offering valuable insights for subsequent investigations.

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Publication Details

Journal
Gels
Published
2026-03-27
DOI
https://doi.org/10.3390/gels12040280
Primary Topic
Drilling and Well Engineering
Type
article
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article

Study on a Thermally Crosslinking Clay-Free Weak Gel Water-Based Drilling Fluid

Yecheng Li, Yuanwei Sun, Yaqi Zheng, Delin Hou et al.
Gels
Drilling and Well Engineering
article

Study on a Thermally Crosslinking Clay-Free Weak Gel Water-Based Drilling Fluid

Yecheng Li, Yuanwei Sun, Yaqi Zheng, Delin Hou, Lei Nie, Ning Huang, Jingping Liu, Taifeng Zhang, Kaihe Lv, Han Yan, Jinsheng Sun
article en

Abstract

In this study, a thermally crosslinking clay-free weak gel water-based drilling fluid based on salt-responsive polymers and crosslinking agents was investigated as a promising and feasible strategy. Firstly, a salt-tolerant polymer was synthesized using N,N-dimethylacrylamide (DMAA), [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfonopropyl)ammonium hydroxide (DMAPS), and acrylamide (AM). BPEI10,000 was selected as the thermal crosslinking agent. The optimal crosslinking was achieved at 180 °C and 36% NaCl, with RMFL at 2.0% and BPEI10,000 at 0.1%. Performance evaluation demonstrated that the crosslinking between RMFL and BPEI10,000 could enhance the AV, PV, and YP of the RMFL(BPEI10,000)/CF-WBDFs after aging at 180 °C for 16 h and reduce FLAPI. The RMFL(BPEI10,000)/CF-WBDFs exhibited appropriate shear-thinning behavior, viscoelasticity, thixotropy, and recoverable viscosity under high-temperature, high-salinity, and high-pressure conditions. Mechanism analysis revealed that RMFL and BPEI10,000 could form a predominantly negatively charged, three-dimensional crosslinking weak gel at high temperatures. The crosslinking weak gel could form dense filter cakes, improving rheological properties and reducing filtration loss of CFWBDFs in high-temperature, high-salinity environments. This paper proposed a novel method to address the technical challenge of rheological performance failure of CFWBDFs, offering valuable insights for subsequent investigations.

GelsVol. 12(4)
China University of Petroleum, East China (CN)
Clean water and sanitation
Openalex Percentile: Top 5%
Drilling and Well Engineering
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