Efficient Access to 5-Acylated Benzoxasilepines Enabled by NHC/Pd Cooperative Catalysis

The termination of the endo-selective cyclization of 2-vinylphenol-derived iodomethylsilyl ether has been limited to hydrogen atom abstraction or transition metal-induced β-hydride elimination, affording non-substituted benzoxasilepines. Herein, we report the efficient...

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2026-01-01
DOI
https://doi.org/10.1039/d6qo00100a
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
Field-Weighted Citation Impact
0.00
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article

Efficient Access to 5-Acylated Benzoxasilepines Enabled by NHC/Pd Cooperative Catalysis

Shi‐Chao Ren, Tingting Li, Ziye Cheng, Lala Wang et al.
Organic Chemistry Frontiers
Catalytic Cross-Coupling Reactions
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Efficient Access to 5-Acylated Benzoxasilepines Enabled by NHC/Pd Cooperative Catalysis

Shi‐Chao Ren, Tingting Li, Ziye Cheng, Lala Wang, Huimin Xia, Jixing Li
article en

Abstract

The termination of the endo-selective cyclization of 2-vinylphenol-derived iodomethylsilyl ether has been limited to hydrogen atom abstraction or transition metal-induced β-hydride elimination, affording non-substituted benzoxasilepines. Herein, we report the efficient...

Organic Chemistry Frontiers
Openalex Percentile: Top 6%
Catalytic Cross-Coupling Reactions
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Efficient Access to 5-Acylated Benzoxasilepines Enabled by NHC/Pd Cooperative Catalysis — Shi‐Chao Ren, Tingting Li, et al. · Organic Chemistry Frontiers (2026) | TGRS Research Map | TGRS