Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: Balancing Lewis acidity and Lewis basicity

The inherent Lewis basic character of 1,2,3-diazaborines (DAB) prevents straightforward conversion of their prevalent B–OH motif into a B–Hal group with BX3 due to competitive ortho-directed C−H borylation. A synthetic...

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Publication Details

Journal
Chemical Communications
Published
2026-01-01
DOI
https://doi.org/10.1039/d6cc01072e
Primary Topic
Organoboron and organosilicon chemistry
Type
article
Field-Weighted Citation Impact
0.00
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article

Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: Balancing Lewis acidity and Lewis basicity

Tim Wellnitz, Krzysztof Radacki, Leonie Wüst, Samuel Nees et al.
Chemical Communications
Organoboron and organosilicon chemistry
article

Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: Balancing Lewis acidity and Lewis basicity

Tim Wellnitz, Krzysztof Radacki, Leonie Wüst, Samuel Nees, Holger Braunschweig
article en

Abstract

The inherent Lewis basic character of 1,2,3-diazaborines (DAB) prevents straightforward conversion of their prevalent B–OH motif into a B–Hal group with BX3 due to competitive ortho-directed C−H borylation. A synthetic...

Chemical Communications
Openalex Percentile: Top 7%
Organoboron and organosilicon chemistry
DOISourceOpenAlex
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Attempted halogenation of ambiphilic 1,2,3-benzodiazaborines: Balancing Lewis acidity and Lewis basicity — Tim Wellnitz, Krzysztof Radacki, et al. · Chemical Communications (2026) | TGRS Research Map | TGRS