Suppression of hysteresis in ultrathin tellurium transistors

Tellurium (Te) is a promising p-type semiconductor but suffers from pronounced electrical hysteresis that limits device stability. The origin of hysteresis in Te field-effect transistors is investigated, and effective suppression strategies are demonstrated. In exposed devices, large hysteresis and abrupt current switching are observed, governed by the direction and range of gate voltage sweeps rather than gate polarity, and are attributed to the dynamic reorientation of dipolar gas molecules adsorbed on the Te surface. Dielectric encapsulation using Al2O3 significantly suppresses gas-induced hysteresis, resulting in improved mobility of ~80 cm2 V-1 s-1 and an ION/IOFF ratio exceeding 105 under ambient conditions. Nevertheless, residual hysteresis associated with charge trapping persists in single-gate devices. To further stabilize channel electrostatics, a dual-gate architecture employing Al2O3 top and bottom dielectrics is implemented, achieving hysteresis below 1 V across a wide range of sweep rates and exhibiting minimal degradation under prolonged bias stress. These results establish a comprehensive understanding of hysteresis in Te and enable reliable, BEOL-compatible p-type transistors for advanced integration.

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Publication Details

Journal
npj 2D Materials and Applications
Published
2026-03-26
DOI
https://doi.org/10.1038/s41699-026-00686-1
Primary Topic
Semiconductor materials and devices
Type
article
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article

Suppression of hysteresis in ultrathin tellurium transistors

Shih-Chieh Chen, Yu‐Lun Chueh, Y. C. Chang, Yen‐Fu Lin et al.
npj 2D Materials and Applications
Semiconductor materials and devices
article

Suppression of hysteresis in ultrathin tellurium transistors

Shih-Chieh Chen, Yu‐Lun Chueh, Y. C. Chang, Yen‐Fu Lin, Der‐Hsien Lien, Shun‐Tsung Lo, Iuliana Radu, K. S. Li, Chia-Chen Chung, Ciao-Fen Chen, Sung-Tsun Wang, Chao-Ching Cheng, Chia-Hung Lo, Tzu-Ting Weng, Terry Y. T. Hung, Tanveer Ahmed, Chan-Yuen Chang
article en

Abstract

Tellurium (Te) is a promising p-type semiconductor but suffers from pronounced electrical hysteresis that limits device stability. The origin of hysteresis in Te field-effect transistors is investigated, and effective suppression strategies are demonstrated. In exposed devices, large hysteresis and abrupt current switching are observed, governed by the direction and range of gate voltage sweeps rather than gate polarity, and are attributed to the dynamic reorientation of dipolar gas molecules adsorbed on the Te surface. Dielectric encapsulation using Al2O3 significantly suppresses gas-induced hysteresis, resulting in improved mobility of ~80 cm2 V-1 s-1 and an ION/IOFF ratio exceeding 105 under ambient conditions. Nevertheless, residual hysteresis associated with charge trapping persists in single-gate devices. To further stabilize channel electrostatics, a dual-gate architecture employing Al2O3 top and bottom dielectrics is implemented, achieving hysteresis below 1 V across a wide range of sweep rates and exhibiting minimal degradation under prolonged bias stress. These results establish a comprehensive understanding of hysteresis in Te and enable reliable, BEOL-compatible p-type transistors for advanced integration.

npj 2D Materials and Applications
National Sun Yat-sen University (TW), National Yang Ming Chiao Tung University (TW), National Chung Hsing University (TW), Korea University (KR), National Tsing Hua University (TW), Taiwan Semiconductor Manufacturing Company (Taiwan) (TW), National Institutes of Applied Research (TW)
Affordable and clean energy
Openalex Percentile: Top 7%
Semiconductor materials and devices
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