Physiochemical Properties Investigation of Thermal–Moisture-Aged Low Voltage PVC Cable Insulation

This study investigates the combined effects of thermal and moisture aging on PVC-insulated low voltage (LV) photovoltaic (PV) cables using an accelerated-aging design to represent realistic PV operating conditions commonly encountered in hot and humid climates. Thermal aging was carried out at 90 °C for five aging cycles, with each thermal cycle followed by controlled moisture injection to simulate moisture stress. The degradation behavior was evaluated using broadband dielectric spectroscopy, FTIR analysis, and Shore D hardness measurements. Changes in dielectric dissipation factor (tanδ) and real permittivity (ε′) were analyzed over a wide frequency range, with 100 kHz selected for its high sensitivity to aging-induced oxidation-related dipolar and interfacial polarization mechanisms. Degradation indices (DI) and degradation rates (DR) were derived from tanδ and correlated with mechanical and chemical changes. The results showed a 5% and 7% increase in tanδ at 100 kHz and in hardness, respectively, with decreases of 68% and 75% in the carbonyl and hydroxyl indices, respectively. Three distinct aging stages were identified: early thermo-oxidation with limited functional impact; mid-stage dehydrochlorination and moisture interaction; and late-stage chain scission, plasticizer loss, and insulation stiffening. The findings demonstrate the importance of climate-specific aging assessment and confirm the effectiveness of integrated electrical, mechanical, and chemical diagnostics for PV cable condition monitoring.