One-Dimensional Mixed-valence Ce(III)/Ce(IV)-Containing Arsenotungstate for Photocatalytic Synthesis of Quinazolines

A novel mixed-valence cerium-containing polyoxometalate, Na18[Ce(III)2(H2O)12Ce(IV)6(μ3-O)4(μ3-OH)4(AsW9O33)4]·33H2O (Ce8As4W36), was synthesized and characterized. Ce8As4W36 is composed of a hexanuclear {Ce(IV)6O8} cluster surrounded by four trivacant Keggin-type [AsW9O33]9- units. These tetramers are further...

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Publication Details

Journal
Chemical Communications
Published
2026-01-01
DOI
https://doi.org/10.1039/d6cc00970k
Primary Topic
Polyoxometalates: Synthesis and Applications
Type
article
Field-Weighted Citation Impact
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article

One-Dimensional Mixed-valence Ce(III)/Ce(IV)-Containing Arsenotungstate for Photocatalytic Synthesis of Quinazolines

Xiao-Chao Huang, Guo-Ping Yang, Hao-Zhe Wang, Yufeng Liu et al.
Chemical Communications
Polyoxometalates: Synthesis and Applications
article

One-Dimensional Mixed-valence Ce(III)/Ce(IV)-Containing Arsenotungstate for Photocatalytic Synthesis of Quinazolines

Xiao-Chao Huang, Guo-Ping Yang, Hao-Zhe Wang, Yufeng Liu, Jun Wu, Haoqi Liu
article en

Abstract

A novel mixed-valence cerium-containing polyoxometalate, Na18[Ce(III)2(H2O)12Ce(IV)6(μ3-O)4(μ3-OH)4(AsW9O33)4]·33H2O (Ce8As4W36), was synthesized and characterized. Ce8As4W36 is composed of a hexanuclear {Ce(IV)6O8} cluster surrounded by four trivacant Keggin-type [AsW9O33]9- units. These tetramers are further...

Chemical Communications
Openalex Percentile: Top 10%
Polyoxometalates: Synthesis and Applications
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One-Dimensional Mixed-valence Ce(III)/Ce(IV)-Containing Arsenotungstate for Photocatalytic Synthesis of Quinazolines — Xiao-Chao Huang, Guo-Ping Yang, et al. · Chemical Communications (2026) | TGRS Research Map | TGRS