Lewis Base/Alkali Metal Halide Co-catalyzed Allylic Alkylation of gem-Diborylalkanes with MBH Carbonates for the Construction of tert-Alkylboronic Esters

A mild and efficient DMAP/KF co-catalyzed allylic alkylation of gem-diborylalkanes with MBH carbonates has been developed, providing a series of tertiary alkylboronate esters in moderate to excellent yields. Moreover, this...

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2026-01-01
DOI
https://doi.org/10.1039/d6qo00181e
Primary Topic
Organoboron and organosilicon chemistry
Type
article
Field-Weighted Citation Impact
0.00
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article

Lewis Base/Alkali Metal Halide Co-catalyzed Allylic Alkylation of gem-Diborylalkanes with MBH Carbonates for the Construction of tert-Alkylboronic Esters

Zhishi Ye, Lei Shi, Bing-Xia Yan, Zhen-Xu Yang et al.
Organic Chemistry Frontiers
Organoboron and organosilicon chemistry
article

Lewis Base/Alkali Metal Halide Co-catalyzed Allylic Alkylation of gem-Diborylalkanes with MBH Carbonates for the Construction of tert-Alkylboronic Esters

Zhishi Ye, Lei Shi, Bing-Xia Yan, Zhen-Xu Yang, Lidong Gong
article en

Abstract

A mild and efficient DMAP/KF co-catalyzed allylic alkylation of gem-diborylalkanes with MBH carbonates has been developed, providing a series of tertiary alkylboronate esters in moderate to excellent yields. Moreover, this...

Organic Chemistry Frontiers
Openalex Percentile: Top 9%
Organoboron and organosilicon chemistry
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Lewis Base/Alkali Metal Halide Co-catalyzed Allylic Alkylation of gem-Diborylalkanes with MBH Carbonates for the Construction of tert-Alkylboronic Esters — Zhishi Ye, Lei Shi, et al. · Organic Chemistry Frontiers (2026) | TGRS Research Map | TGRS