Synthesis and Properties of Fully Biobased Plastics from Biuret and Diamines

In this work, fully biobased polybiurets (PBUs) were prepared from the polymerizations of biuret, a green and environmentally friendly chemical derived from urea, with 1,10-decanediamine and 1,6-hexanediamine. No solvent and no catalyst is needed in such polymerizations. Both biuret and urea functions can be observed in the obtained products. The PBUs possess higher glass transition temperature than the corresponding polyureas (~40 °C higher). The strength at break achieves as high as 77 MPa. The mechanical and thermal properties of the PBUs can be feasibly tuned by altering the proportions of the two diamines. It is provided in this work a new strategy in the construction of biobased polymers with high performance.