Design of Hybrid Steric α-Diimine Nickel Precatalysts with Intramolecular π-π Interactions for the Synthesis of Polyethylene Elastomers

A series of hybrid steric α-diimine Ni(II) precatalysts incorporating a rigid diarylmethyl group and a flexible isopropyl substituent were designed and synthesized for ethylene polymerization. Single-crystal X-ray diffraction analyses revealed...

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Publication Details

Journal
Dalton Transactions
Published
2026-01-01
DOI
https://doi.org/10.1039/d6dt00369a
Primary Topic
Organometallic Complex Synthesis and Catalysis
Type
article
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article

Design of Hybrid Steric α-Diimine Nickel Precatalysts with Intramolecular π-π Interactions for the Synthesis of Polyethylene Elastomers

Zhongbao Jian, Yuxing Zhang, Xiaoqiang Hu, Jingfeng Yue
Dalton Transactions
Organometallic Complex Synthesis and Catalysis
article

Design of Hybrid Steric α-Diimine Nickel Precatalysts with Intramolecular π-π Interactions for the Synthesis of Polyethylene Elastomers

Zhongbao Jian, Yuxing Zhang, Xiaoqiang Hu, Jingfeng Yue
article en

Abstract

A series of hybrid steric α-diimine Ni(II) precatalysts incorporating a rigid diarylmethyl group and a flexible isopropyl substituent were designed and synthesized for ethylene polymerization. Single-crystal X-ray diffraction analyses revealed...

Dalton Transactions
Openalex Percentile: Top 10%
Organometallic Complex Synthesis and Catalysis
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Design of Hybrid Steric α-Diimine Nickel Precatalysts with Intramolecular π-π Interactions for the Synthesis of Polyethylene Elastomers — Zhongbao Jian, Yuxing Zhang, et al. · Dalton Transactions (2026) | TGRS Research Map | TGRS