Three-Component Carbosulfonylation of Alkenes via Single-Atom Nickel Photocatalysis
A heterogeneous metallaphotocatalytic carbosulfonylation of vinyl amides has been developed using a recyclable bifunctional poly(heptazine imide) (PHI) photocatalyst bearing single-atom Ni sites (bpyNi<sub>SA</sub>-PHI). This robust protocol enables efficient and sustainable access to diverse vicinal aminosulfones at exceptionally low catalyst loadings (0.43-0.86 mol %) under mild conditions.
Authors
- Yunfei Cai (ORCID: https://orcid.org/0000-0003-4823-8221)
- Mingyao Wu
- Hao Wang (ORCID: https://orcid.org/0000-0001-6881-9977)
- Wei J. Wang (ORCID: https://orcid.org/0000-0002-4848-7394)
- Yurong Tang
- Qian Yang
Institutions
- Chongqing University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-03-23
- DOI
- https://doi.org/10.1021/acs.orglett.6c00998
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00