Phosphine-catalyzed β-C(sp <sup>3</sup> )–H functionalization of cyclic amines <i>via</i> a halogen based frustrated radical pairs approach
A metal-free, phosphine-catalyzed strategy for the β-position C(sp³)–H functionalization of cyclic amines, enabled by a novel frustrated radical pairs (FRPs) mechanism has been developed.
Authors
- Shicheng Dong (ORCID: https://orcid.org/0000-0001-9309-762X)
- Zhuan Zhang (ORCID: https://orcid.org/0000-0003-4841-4109)
- Xiaodan Meng
- Taoyuan Liang
- Xiaoxiang Zhang
- Chenrui Liu
- Yukun Xie
- Jiaming Tan
Institutions
- Guangxi University (CN)
Publication Details
- Journal
- Chemical Science
- Published
- 2026-01-01
- DOI
- https://doi.org/10.1039/d6sc00591h
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00