Moments of the Sorption Kinetic Curve of Non-Integer Order

It is proposed for the first time to use non-integer order moments for the analysis of the sorption kinetics of gases and liquids by membranes and adsorbents. An analytical formula for the moment of the gas sorption kinetic curve by a homogeneous membrane of any non-negative order has been obtained. It is shown that the first and second order moments obtained using this formula coincide with known analytical expressions for these moments. An expression has been derived for calculating the diffusion coefficient using a non-integer order moment. Through mathematical modeling, it has been demonstrated that the error in determining the diffusion coefficient depends on the total measurement time of the sorption kinetic curve and the order of the kinetic curve moment.

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Publication Details

Journal
Membranes and Membrane Technologies
Published
2025-12-01
DOI
https://doi.org/10.1134/s2517751625600967
Primary Topic
Membrane Separation and Gas Transport
Type
article
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article

Moments of the Sorption Kinetic Curve of Non-Integer Order

V. V. Ugrozov
Membranes and Membrane Technologies
Membrane Separation and Gas Transport
article

Moments of the Sorption Kinetic Curve of Non-Integer Order

V. V. Ugrozov
article en

Abstract

It is proposed for the first time to use non-integer order moments for the analysis of the sorption kinetics of gases and liquids by membranes and adsorbents. An analytical formula for the moment of the gas sorption kinetic curve by a homogeneous membrane of any non-negative order has been obtained. It is shown that the first and second order moments obtained using this formula coincide with known analytical expressions for these moments. An expression has been derived for calculating the diffusion coefficient using a non-integer order moment. Through mathematical modeling, it has been demonstrated that the error in determining the diffusion coefficient depends on the total measurement time of the sorption kinetic curve and the order of the kinetic curve moment.

Membranes and Membrane TechnologiesVol. 7(6)
Financial University (RU)
Openalex Percentile: Top 37%
Membrane Separation and Gas Transport
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