Impact of differential stress on fracture due to volume increasing hydration

Abstract. The volume increase that accompanies many hydration reactions can stress and fracture the surrounding rock, a process commonly called reaction-induced fracturing. Reaction-induced fracturing accelerates the rate of hydration by creating new pathways for fluids to migrate into reactive rock and by generating new reactive surface areas. The evolution of reaction-induced fractures also depends on the background stress state, which varies among different tectonic environments. We investigate the impact of tectonic stresses on reaction-induced fracturing using 2-D hydraulic-chemical-mechanical distinct element models. The results indicate that the general pattern of reaction-induced fractures depends on the orientation of background tectonic stresses relative to fluid-supplying channels. A spalling fracture pattern characterized by short cracks parallel to and along fluid-supplying channels occurs when the maximum principal tectonic stress is parallel to the channels whereas a branching fracture pattern characterized by long tensile cracks that propagate in a hierarchical manner into unreacted parts of the rock is expected when the tectonic stress is hydrostatic or when the maximum principal tectonic stress is normal to fluid-supplying channels. Spalling localizes hydration and fluid flow along the channels whereas branching promotes spatially extensive hydration and fluid flow away from the fluid supply. The results indicate tectonic stresses may guide the hydration distribution in the oceanic lithosphere at mid-ocean ridges and outer rises and in the cold mantle wedge corner in subduction zones.