How spontaneous electrowetting and surface charging affect drop motion

Water drops sliding on hydrophobic surfaces spontaneously separate charges at their rear. It is unclear how this charge separation affects the contact angles of a sliding drop. We slide grounded and insulated drops on hydrophobic surfaces at low capillary numbers (\leq 10^{-4}). We find that drop charge leads to spontaneous electrowetting, which decreases the contact angles. Additionally, the deposited charges lead to a surface charge effect and decrease the contact angle. Both phenomena compensate each other at the receding contact line, resulting in an insignificant change in the receding contact angle of a sliding drop.

Authors

Publication Details

Journal
Physical Review Letters
Published
2026-03-17
DOI
https://doi.org/10.1103/9mzt-v9cl
Primary Topic
Electrowetting and Microfluidic Technologies
Type
article
Field-Weighted Citation Impact
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article

How spontaneous electrowetting and surface charging affect drop motion

Anonymous
Physical Review Letters
Electrowetting and Microfluidic Technologies
article

How spontaneous electrowetting and surface charging affect drop motion

Anonymous
article en

Abstract

Water drops sliding on hydrophobic surfaces spontaneously separate charges at their rear. It is unclear how this charge separation affects the contact angles of a sliding drop. We slide grounded and insulated drops on hydrophobic surfaces at low capillary numbers (\leq 10^{-4}). We find that drop charge leads to spontaneous electrowetting, which decreases the contact angles. Additionally, the deposited charges lead to a surface charge effect and decrease the contact angle. Both phenomena compensate each other at the receding contact line, resulting in an insignificant change in the receding contact angle of a sliding drop.

Physical Review Letters
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Electrowetting and Microfluidic Technologies
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