Paired Electrolysis-Promoted Ni-Catalyzed Decarboxylative Cross-Couplings of Potassium Malonate Monoesters with Aryl Bromides
We report a paired electrolysis-promoted Ni-catalyzed decarboxylative cross-coupling of aryl bromides with potassium malonate monoesters. Carried out in an undivided electrolytic cell under mild reaction conditions, this strategy exhibits broad compatibility with a wide range of aryl/heteroaryl and vinyl bromides, offering a practical and efficient protocol for the synthesis of α-aryl esters.
Authors
- Jinzhong Yao (ORCID: https://orcid.org/0000-0003-2444-7731)
- S. H. Zhang (ORCID: https://orcid.org/0000-0003-1127-7876)
- Shuai Lv
- Hongwei Zhou
Institutions
- Jiaxing University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-03-16
- DOI
- https://doi.org/10.1021/acs.orglett.6c00805
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00