A Laser-Engineered Architecture for a Thermally Switchable Slippery Surface with Durable Anti-Corrosion and Self-Healing Properties

Slippery lubricant-infused surfaces (SLIPS) suffer from rapid lubricant depletion, severely limiting their durability in practical applications. To overcome this, we propose a laser-engineered hierarchical architecture that physically locks a solid paraffin lubricant, creating a multifunctional coating with thermally switchable slipperiness. Using femtosecond laser ablation, a hierarchical porous structure (HPS) was fabricated on an aluminum alloy, followed by silanization to achieve superhydrophobicity (contact angle ≈ 154.7°) for enhanced paraffin wetting. The resulting HPS-P coating exhibits thermally switchable adhesion: water droplets pin on the solid surface (sliding angle > 90°) but slide readily (<10°) upon heating above the paraffin’s melting point. The coating demonstrates rapid self-healing, repairing severe scratches within 100 s via molten paraffin flow. The HPS-P coating provides excellent corrosion protection, with its corrosion current density reduced by six orders of magnitude compared to bare aluminum and an inhibition efficiency approaching 100%. This work provides a durable, thermally responsive coating strategy with integrated anti-corrosion and self-healing functions for extreme environments.