HAT-Initiated Fragmentation of 4-(Dimethylamino)-1-((3-methylbut-2-en-1-yl)oxy)-3-phenylbut-3-en-2-one
An alkene-tethered enaminone 7 was synthesized in four steps from bromoacetic acid and 3,3-dimethylallyl alcohol. The enaminone was fully characterized, including UV-Vis spectra. TBADT-catalyzed HAT of the alkene-tethered enaminone initiated a fragmentation that yielded the literature-known phenylacetone-derived enaminone.
Authors
- Franc Požgan (ORCID: https://orcid.org/0000-0001-6040-294X)
- Uroš Grošelj (ORCID: https://orcid.org/0000-0002-5186-9879)
- Bogdan Štefane (ORCID: https://orcid.org/0000-0002-8709-9853)
- Nejc Petek (ORCID: https://orcid.org/0000-0003-3331-4885)
- Andrej Bogataj
- Jurij Svete
- Luka Ciber
Institutions
- University of Ljubljana (SI)
Publication Details
- Journal
- Molbank
- Published
- 2026-03-11
- DOI
- https://doi.org/10.3390/m2149
- Primary Topic
- Synthesis and Characterization of Pyrroles
- Type
- article
- Field-Weighted Citation Impact
- 0.00