Carbene Intermediates from 1-Methylimidazole and Acylphenylacetylenes in Reaction with Elemental Sulfur: One-Pot Assembly of Functionalized Imidazole-2-thiones
A one-pot approach was proposed for the synthesis of functionalized 1-alkenyl-3-methylimidazole-2-thiones (yields up to 30%) by intercepting the carbene, generated in situ from 1-methylimidazole and acylphenylacetylenes, with elemental sulfur.
Authors
- Lina P. Nikitina (ORCID: https://orcid.org/0000-0002-7171-1868)
- Kseniya V. Belyaeva (ORCID: https://orcid.org/0000-0002-7880-7555)
- Igor Ushakov (ORCID: https://orcid.org/0000-0002-6988-9261)
- Veronika S. Saliy
- Andrey V. Afonin
Institutions
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
Publication Details
- Journal
- Russian Journal of General Chemistry
- Published
- 2026-03-11
- DOI
- https://doi.org/10.1134/s1070363225607240
- Primary Topic
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00