Multiscale Rheological Properties of Pavement Asphalt: A State-of-the-Art Review

Asphalt rheological properties are fundamental to pavement performance, yet their accurate assessment requires multi-scale characterization due to asphalt’s inherent complexity. This article reviews the connections between asphalt rheology across chemical, microstructural, and macro-mechanical scales, employing a methodological analysis of supramolecular and colloidal models for micro-scale behavior and dynamic shear rheometry for macro-scale properties. Current research confirms asphalt as a complex multiphase continuum, where micro-scale rheology is explained by intermolecular interactions and colloidal structures, while macro-scale analysis successfully characterizes linear viscoelasticity through established empirical and mechanical models. However, the study identifies critical gaps: nonlinear viscoelastic characterization under large-amplitude oscillatory shear (LAOS) remains underdeveloped, and fundamental issues like directly probing molecular interactions and the origin of microstructures like the “bee structure” are unresolved. The primary conclusion is that a comprehensive understanding of asphalt rheology hinges on future research that integrates experimental and simulation data across these scales to bridge the gaps between chemical composition, microstructure, and macroscopic performance.