Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?

• Viscosity–temperature data of borosilicate melts were systematically analyzed. • AM and MYEGA models outperform VFT in viscosity extrapolation. • Low-temperature viscosity data provide more reliable extrapolations toward high-temperature regions than the opposite. • A new dimensionless parameter evaluates extrapolation reliability. • Including the calorimetric glass transition temperature improves the accuracy of high-temperature partial datasets. Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter ( φ ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.

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Publication Details

Journal
Journal of Non-Crystalline Solids
Published
2026-03-04
DOI
https://doi.org/10.1016/j.jnoncrysol.2026.124047
Primary Topic
Glass properties and applications
Type
article
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article

Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?

Ricardo F. Lancelotti, Rafael Baságlia Rosante, Donald B. Dingwell, Luiz Pereira et al.
Journal of Non-Crystalline Solids
Glass properties and applications
article

Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?

Ricardo F. Lancelotti, Rafael Baságlia Rosante, Donald B. Dingwell, Luiz Pereira, Edgar D. Zanotto
article en

Abstract

• Viscosity–temperature data of borosilicate melts were systematically analyzed. • AM and MYEGA models outperform VFT in viscosity extrapolation. • Low-temperature viscosity data provide more reliable extrapolations toward high-temperature regions than the opposite. • A new dimensionless parameter evaluates extrapolation reliability. • Including the calorimetric glass transition temperature improves the accuracy of high-temperature partial datasets. Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter ( φ ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.

Journal of Non-Crystalline SolidsVol. 681
Zhejiang International Studies University (CN), Universidade Federal de São Carlos (BR)
Zero hunger
Openalex Percentile: Top 34%
Glass properties and applications
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Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts? — Ricardo F. Lancelotti, Rafael Baságlia Rosante, et al. · Journal of Non-Crystalline Solids (2026) | TGRS Research Map | TGRS