Heck Coupling of 10,10′-Dibromo-9,9′-bianthracene with Para-Substituted Styrenes—Evaluation of the Reaction as a Method for Synthesising Polyunsaturated Bianthracene Derivatives

10,10′-dibromo-9,9′-bianthracene undergoes efficient Heck coupling with a series of para-substituted styrenes in the presence of a simple palladium-based catalytic system. The reaction proceeds with complete regio- and stereoselectivity. The disadvantage of this method is the minor competitive catalytic hydrodebromination.

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Publication Details

Journal
Catalysts
Published
2026-03-02
DOI
https://doi.org/10.3390/catal16030222
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
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article

Heck Coupling of 10,10′-Dibromo-9,9′-bianthracene with Para-Substituted Styrenes—Evaluation of the Reaction as a Method for Synthesising Polyunsaturated Bianthracene Derivatives

Anna Chojnacka, Szymon Rogalski, Angelika Mieszczanin, Agnieszka Czapik et al.
Catalysts
Catalytic Cross-Coupling Reactions
article

Heck Coupling of 10,10′-Dibromo-9,9′-bianthracene with Para-Substituted Styrenes—Evaluation of the Reaction as a Method for Synthesising Polyunsaturated Bianthracene Derivatives

Anna Chojnacka, Szymon Rogalski, Angelika Mieszczanin, Agnieszka Czapik, Cezary Pietraszuk, Stanisław Krompiec
article en

Abstract

10,10′-dibromo-9,9′-bianthracene undergoes efficient Heck coupling with a series of para-substituted styrenes in the presence of a simple palladium-based catalytic system. The reaction proceeds with complete regio- and stereoselectivity. The disadvantage of this method is the minor competitive catalytic hydrodebromination.

CatalystsVol. 16(3)
Silesian University of Technology (PL), Adam Mickiewicz University in Poznań (PL), University of Silesia in Katowice (PL)
Clean water and sanitation
Openalex Percentile: Top 36%
Catalytic Cross-Coupling Reactions
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Heck Coupling of 10,10′-Dibromo-9,9′-bianthracene with Para-Substituted Styrenes—Evaluation of the Reaction as a Method for Synthesising Polyunsaturated Bianthracene Derivatives — Anna Chojnacka, Szymon Rogalski, et al. · Catalysts (2026) | TGRS Research Map | TGRS