Electromagnetic Interference Shielding Material from Grape Seeds: A Sustainable Pyrolysis Route
Grape marcs represent one of the most effectively exploited biowaste resources through cascade valorization approaches, in which byproducts are processed via multiple sequential steps such as extraction, bio-treatment, and pyrolysis. In this study, we present a novel route for producing graphitic carbon (GC) from grape seeds derived from exhausted marc via pyrolysis. We integrate hydropyrolysis and CO2 methanation in a one-pot methodology to valorize both bio-oil and gaseous pyrolysis byproducts. The GC obtained through pyrolysis is evaluated in GC/Polytetrafluoroethylene (PTFE) composites as an electromagnetic interference (EMI) shielding material across the X-band frequency range (8–12 GHz). This work demonstrates a viable and eco-friendly pathway to upcycle abundant biomass into a lightweight, sustainable, and highly tunable material, which represents a promising candidate for effective EMI shielding while simultaneously mitigating process emissions.
Authors
- Pasquale Crupi (ORCID: https://orcid.org/0000-0001-6457-8619)
- Stefano Dicorato
- Giovanni Carlo Bruno (ORCID: https://orcid.org/0000-0002-1023-9424)
- Francesco Nocito (ORCID: https://orcid.org/0000-0002-3186-7526)
- Giuseppe Valerio Bianco (ORCID: https://orcid.org/0000-0002-0986-1531)
- Chiara Ingrosso (ORCID: https://orcid.org/0000-0003-4912-8673)
- Giovanni Magno (ORCID: https://orcid.org/0000-0003-2985-1215)
- A. D’Orazio (ORCID: https://orcid.org/0000-0002-5891-7036)
- Angela Dibenedetto
Institutions
- Istituto di Nanotecnologia (IT)
- Consorzio Interuniversitario Reattività Chimica e Catalisi (IT)
- Institute for Chemical and Physical Processes (IT)
- University of Bari Aldo Moro (IT)
- Polytechnic University of Bari (IT)
- University of Palermo (IT)
Publication Details
- Journal
- Catalysts
- Published
- 2026-03-02
- DOI
- https://doi.org/10.3390/catal16030226
- Primary Topic
- Electromagnetic wave absorption materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- European Commission
- Ministero dell’Istruzione, dell’Università e della Ricerca