Electromagnetic Interference Shielding Material from Grape Seeds: A Sustainable Pyrolysis Route

Grape marcs represent one of the most effectively exploited biowaste resources through cascade valorization approaches, in which byproducts are processed via multiple sequential steps such as extraction, bio-treatment, and pyrolysis. In this study, we present a novel route for producing graphitic carbon (GC) from grape seeds derived from exhausted marc via pyrolysis. We integrate hydropyrolysis and CO2 methanation in a one-pot methodology to valorize both bio-oil and gaseous pyrolysis byproducts. The GC obtained through pyrolysis is evaluated in GC/Polytetrafluoroethylene (PTFE) composites as an electromagnetic interference (EMI) shielding material across the X-band frequency range (8–12 GHz). This work demonstrates a viable and eco-friendly pathway to upcycle abundant biomass into a lightweight, sustainable, and highly tunable material, which represents a promising candidate for effective EMI shielding while simultaneously mitigating process emissions.

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Publication Details

Journal
Catalysts
Published
2026-03-02
DOI
https://doi.org/10.3390/catal16030226
Primary Topic
Electromagnetic wave absorption materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Electromagnetic Interference Shielding Material from Grape Seeds: A Sustainable Pyrolysis Route

Pasquale Crupi, Stefano Dicorato, Giovanni Carlo Bruno, Francesco Nocito et al.
Catalysts
Electromagnetic wave absorption materials
article

Electromagnetic Interference Shielding Material from Grape Seeds: A Sustainable Pyrolysis Route

Pasquale Crupi, Stefano Dicorato, Giovanni Carlo Bruno, Francesco Nocito, Giuseppe Valerio Bianco, Chiara Ingrosso, Giovanni Magno, A. D’Orazio, Angela Dibenedetto
article en

Abstract

Grape marcs represent one of the most effectively exploited biowaste resources through cascade valorization approaches, in which byproducts are processed via multiple sequential steps such as extraction, bio-treatment, and pyrolysis. In this study, we present a novel route for producing graphitic carbon (GC) from grape seeds derived from exhausted marc via pyrolysis. We integrate hydropyrolysis and CO2 methanation in a one-pot methodology to valorize both bio-oil and gaseous pyrolysis byproducts. The GC obtained through pyrolysis is evaluated in GC/Polytetrafluoroethylene (PTFE) composites as an electromagnetic interference (EMI) shielding material across the X-band frequency range (8–12 GHz). This work demonstrates a viable and eco-friendly pathway to upcycle abundant biomass into a lightweight, sustainable, and highly tunable material, which represents a promising candidate for effective EMI shielding while simultaneously mitigating process emissions.

CatalystsVol. 16(3)
Istituto di Nanotecnologia (IT), Consorzio Interuniversitario Reattività Chimica e Catalisi (IT), Institute for Chemical and Physical Processes (IT), University of Bari Aldo Moro (IT), Polytechnic University of Bari (IT), University of Palermo (IT)
European Commission, Ministero dell’Istruzione, dell’Università e della Ricerca
Responsible consumption and production
Openalex Percentile: Top 41%
Electromagnetic wave absorption materials
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