Selective Conversion of HMF to OBMF with Cerium-Modified Graphene Oxide Catalysts

<p class="zetMetni"><span lang="EN-US">This studyinvestigates the catalytic conversion of 5-hydroxymethylfurfural (HMF) into5,5-(Oxybis(methylene))-bis-2-furfural (OBMF) using graphene oxide (GO) andmetal-doped graphene oxide catalysts (GO-Ce, GO-Ce-Fe, GO-Ce-Ni). The catalystswere synthesized using a Tour's method and characterized through FTIR, XRD,SEM, and TEM, confirming effective Ce doping and cerium oxide nanoparticledispersion on GO. The GO-Ce catalyst achieved a maximum OBMF yield of 97% at140°C over 12 hours. GC-MS and NMR analyses validated the high conversionefficiency of OBMF. Comparative studies showed GO-Ce's superior selectivity andstability over other catalysts.</span><span lang="EN-GB"><o:p></o:p></span>

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Publication Details

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Van Yüzüncü Yıl University Academic Data Management System
Published
2025-11-25
Primary Topic
Catalysis for Biomass Conversion
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article
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article

Selective Conversion of HMF to OBMF with Cerium-Modified Graphene Oxide Catalysts

Muhammad Sohail Ahmad, Halil Durak, Tetsuya Kida, Imam Sahroni
Van Yüzüncü Yıl University Academic Data Management System
Catalysis for Biomass Conversion
article

Selective Conversion of HMF to OBMF with Cerium-Modified Graphene Oxide Catalysts

Muhammad Sohail Ahmad, Halil Durak, Tetsuya Kida, Imam Sahroni
article en

Abstract

<p class="zetMetni"><span lang="EN-US">This studyinvestigates the catalytic conversion of 5-hydroxymethylfurfural (HMF) into5,5-(Oxybis(methylene))-bis-2-furfural (OBMF) using graphene oxide (GO) andmetal-doped graphene oxide catalysts (GO-Ce, GO-Ce-Fe, GO-Ce-Ni). The catalystswere synthesized using a Tour's method and characterized through FTIR, XRD,SEM, and TEM, confirming effective Ce doping and cerium oxide nanoparticledispersion on GO. The GO-Ce catalyst achieved a maximum OBMF yield of 97% at140°C over 12 hours. GC-MS and NMR analyses validated the high conversionefficiency of OBMF. Comparative studies showed GO-Ce's superior selectivity andstability over other catalysts.</span><span lang="EN-GB"><o:p></o:p></span>

Van Yüzüncü Yıl University Academic Data Management System
Openalex Percentile: Top 37%
Catalysis for Biomass Conversion
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