Study on Ammonia Nitrogen Adsorption Performance and Mechanism of Modified Clinoptilolite

Ammonia nitrogen stands as a pivotal water quality indicator within the frameworks of aquatic ecological quality assessment and aquatic ecological governance systems. This study focuses on the adsorption method, selecting four inorganic adsorbents-clinoptilolite, volcanic rock, bentonite, and fly ash-as research subjects, and introduces rare earth modifiers for rare earth-loading modification. Various modifications were applied to the adsorbents to enhance their ammonia nitrogen adsorption efficacy. Combined with material characterization, the microscopic features and adsorption behaviors of the adsorbents were elucidated, aiming to provide a theoretical foundation for addressing practical engineering challenges and to screen out the optimal inorganic adsorbent and the most effective modification protocol. Based on the experimental findings, cerium chloride modification can significantly enhance the ammonia nitrogen adsorption performance of clinoptilolite. Under the optimal preparation conditions (cerium chloride concentration: 1.0%, solid-liquid ratio: 1:40, pH = 9), the ammonia nitrogen removal efficiency reaches 85.45%. This modification process leads to the formation of new substances: a large amount of cerium oxide and cerium hydroxide are loaded onto the surface of clinoptilolite, which contributes to the increases in specific surface area (21.92 m²/g), average pore diameter (12.27 nm), and total pore volume (0.07 cm³/g). Furthermore, during the modification, cerium hydroxide undergoes hydroxylation, rendering the clinoptilolite surface negatively charged-this facilitates the adsorption of ammonia nitrogen via electrostatic interaction. Notably, the characteristic structural peaks of clinoptilolite remain unchanged before and after modification, indicating that the modification primarily acts on the material surface. This not only improves the ammonia nitrogen adsorption efficiency but also preserves the structural stability of clinoptilolite.