Effect of Diamond Content on Microstructure and Wear/Corrosion Resistance of CoCuNiTi + x Diamond (C) (x = 0, 0.5, and 1.0 wt.%) High-Entropy Alloy Coatings

CoCuNiTi HEACs reinforced by different diamond contents were prepared on the surface of 45 steel substrate by laser cladding. Their phase composition, microstructure, elemental composition, and wear/corrosion resistance were investigated using XRD, OM, SEM, EDS, a friction and wear testing machine, and an electrochemical workstation, respectively. The results show that after adding diamond, the phase composition of the sample transforms from the original dual-phase structure of the FCC main phase and BCC to the dual-phase structure of the BCC main phase and FCC. With an increase in the diamond content, the diffraction peak intensity of the alloy phases first increases and then decreases. This behavior is related to the significant enhancement of the alloy phase crystallinity with low diamond addition and the intensified crystal lattice distortion caused by excessive diamond addition. The CoCuNiTi + x Diamond (C) (x = 0, 0.5, and 1.0 wt.%) high-entropy alloys have a dendritic structure. After the addition of diamond, no hole defects were observed in the microstructure, and the dendritic structure was significantly refined. Ti and C are enriched in the primary phase, Cu is enriched in the interdendrite regions, and Co exhibits the highest concentration in the dendrite regions. The segregation coefficients of Ni in all three alloys are relatively small. As the diamond content increases, the friction coefficient of the samples decreases significantly. The 1 wt.% diamond sample exhibits the best wear resistance, primarily owing to the combined effects of superhard phase strengthening, solid solution strengthening, and fine grain strengthening resulting from diamond addition. The sample with 0.5 wt.% diamond addition has the lowest self-corrosion current density, highest polarization resistance, and lowest annual corrosion rate, indicating the best corrosion resistance. This performance is mainly attributed to the refinement of the microstructure, reduction in defects, and formation of a dense passivation film caused by the addition of a small amount of diamond.