Analysis of Hydrochemical Characteristics and Groundwater Quality Assessment in the North China Plain Region

The North China Plain is one of the largest plains in China, where domestic water supply, agricultural irrigation, and industrial production rely on groundwater resources. Groundwater quality is increasingly affected by the combined effects of intense human activity and geological conditions. To ensure sustainable groundwater utilization, it is crucial to investigate the hydrogeochemical processes linked to hydrogeological conditions. In this study, 85 samples were collected from cold wells and 56 samples from geothermal wells in North China. By integrating self-organizing mapping (SOM), hydrochemical and isotopic analysis, nitrate distribution, water quality index (WQI), and human health risk assessment (HHRA) methodologies, we systematically evaluated the spatial variability of groundwater quality and the associated health risks in the region. Hydrochemical analysis indicates that groundwater recharge is primarily driven by atmospheric precipitation. Shallow cold groundwater in Cluster 1 exhibited a mixed phase, whereas geothermal water in Clusters 2 and 3 and cold groundwater in Cluster 4 predominantly displayed a Na-Cl type. Cation exchange processes are the primary factors controlling ion composition. Water quality assessment studies indicate that 75.15% of the groundwater is suitable for drinking. The average water quality index of the geothermal water was higher than that of the cold water. Shallow groundwater in plains is significantly affected by agricultural activities, typically manifested as elevated NO3− concentrations. Arsenic and boron are the primary non-carcinogenic risk pollutants in geothermal water, and children are more vulnerable than adults. The non-carcinogenic risk zones for cold wells were primarily distributed in Shijiazhuang, Baoding, and the coastal areas downstream of the Yellow River. Tianjin has high-risk geothermal water. Therefore, effective strategies must be implemented to protect this valuable water resource and achieve sustainable development in the region.