Machine Learning-Based Prediction of Boron Desorption in Acidic Tea-Growing Soils

In acidic tea soil, boron (B) adsorption and desorption processes are dominated by the complex relationship between soil acidity, mineralogy, and organic matter. This study investigated B adsorption–desorption behavior in five acidic tea soils (pH 3.8–5.6) collected from the Eastern Black Sea region of Türkiye and evaluated the potential of machine learning (ML) algorithms to predict B desorption. Laboratory batch experiments were conducted using five initial B concentrations, and adsorption data were interpreted using the Langmuir isotherm model. Adsorption experiments indicated that B interacted with Fe/Al-oxide-containing clay minerals, which had low but favorable binding affinity, as indicated by Langmuir maximum adsorption capacities (Qmax) ranging from 46.5 to 181.8 mg kg−1. Desorption experiments revealed a high degree of reversibility, particularly in soils with lower adsorption capacities, ensuring potential B leaching. To capture the governing B desorption, six machine learning (ML) algorithms—Extreme Gradient Boosting (XGBoost), Random Forest (RF), Support Vector Regression (SVR), Gaussian Process Regression (GP), Elastic Net Regression (EN), and Multivariate Adaptive Regression Splines (MARS)—were trained on 75 data points. Among the tested models, Elastic Net showed the highest predictive accuracy (R2 = 0.735). This model does not replace adsorption experiments. It offers a within-assay determination of desorption given measured adsorption, which may reduce the requirement for separate desorption equilibration and analyses. Permutation importance analysis identified B_ads as the dominant predictor of B desorption, with smaller contributions from pH_ads and EC_ads. The results demonstrate that integrating laboratory experiments with machine learning provides an effective framework for predicting B mobility in acidic tea soils, offering a parameterized experimental framework for describing boron desorption behavior in acidic tea soils.