Sustainable Concrete for Rigid Pavements Using Alkali-Activated Recycled Pumice: Strength and Carbonation Assessment

This study investigates alkali-activated recycled pumice as a sustainable cement replacement for hydraulic concrete used in rigid pavements. Cement was replaced at 15%, 25%, and 50% by mass and activated using NaOH solutions at 1 N, 0.5 N, and 0.25 N, resulting in nine mixture variants. Mechanical performance was assessed through compressive strength at 7, 14, and 28 days, and flexural strength at 28 days. Durability was evaluated via natural carbonation depth at 210 and 1090 days. X-ray diffraction (XRD) identified aluminosilicate phases in the pumice, supporting its alkali-reactive potential. Mixtures with 15% pumice replacement achieved compressive strengths up to 20.99 MPa, comparable to the control mix (20.45 MPa), whereas 25% and 50% replacements produced moderate strength reductions. Flexural strength in 15% mixtures (7.38–7.44 MPa) was also comparable to the control (7.30 MPa), while higher replacement levels reduced flexural performance. Carbonation resistance improved for mixtures with an optimized alkaline-to-pumice ratio (APR, defined as NaOH concentration relative to pumice content) between 0.0167 and 0.02, indicating more balanced activation and reduced CO2 ingress. Overall, alkali-activated recycled pumice enables partial cement replacement while maintaining mechanical performance and carbonation resistance at 15% substitution, supporting circular economy strategies and lowering the carbon footprint of rigid pavement concrete.