Cost-effective non-precious nickel borate nanorods for integrated energy and environmental applications

For the sustainable progress, we need to develop affordable, high-performance catalysts that address energy conversion and environmental remediation simultaneously. To meet this challenge, we prepared non-precious nickel borate nanorods using a facile method, providing a high-performance alternative to noble-metal catalysts. Their unique one-dimensional (1D) structure offers an optimal geometric framework that enhances the active surface sites accessibility and promotes efficient charge transfer. The prepared catalyst exhibited excellent performance, yielding a hydrogen production rate of 2181.8 ml min −1 g −1 via NaBH 4 hydrolysis at room temperature, a performance comparable to many noble-metal benchmarks. In addition, the nanorods exhibited rapid environmental remediation capabilities, achieving the pseudo-first order degradation of 4-nitrophenol in 75 s and methylene blue within 25 min. This improved catalytic performance may be attributed to the synergistic electronic coupling between Ni and B species, which lowers the activation energy and enhances structural stability. By harnessing the 1D nanorod framework's, morphological advantages, this work offers a scalable and robust solution for integrated energy conversion and pollutant mitigation. • Bifunctional nickel boate nanorods were synthesized using a solid sate reduction method. • Nickel boate nanorods exhibit superior H 2 production via sodium borohydride hydrolysis. • Catalysts efficiently reduce 4-nitrophenol and methylene blue pollutant. • The nanorods exhibit excellent catalytic stability and reusability over multiple cycles. • Nickel boate nanorods are cost-effective catalyst for green energy and environmental remediation applications.

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Publication Details

Journal
International Journal of Hydrogen Energy
Published
2026-02-19
DOI
https://doi.org/10.1016/j.ijhydene.2026.154079
Primary Topic
Nanomaterials for catalytic reactions
Type
article
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article

Cost-effective non-precious nickel borate nanorods for integrated energy and environmental applications

Waseem Raza, Khalid Umar
International Journal of Hydrogen Energy
Nanomaterials for catalytic reactions
article

Cost-effective non-precious nickel borate nanorods for integrated energy and environmental applications

Waseem Raza, Khalid Umar
article en

Abstract

For the sustainable progress, we need to develop affordable, high-performance catalysts that address energy conversion and environmental remediation simultaneously. To meet this challenge, we prepared non-precious nickel borate nanorods using a facile method, providing a high-performance alternative to noble-metal catalysts. Their unique one-dimensional (1D) structure offers an optimal geometric framework that enhances the active surface sites accessibility and promotes efficient charge transfer. The prepared catalyst exhibited excellent performance, yielding a hydrogen production rate of 2181.8 ml min −1 g −1 via NaBH 4 hydrolysis at room temperature, a performance comparable to many noble-metal benchmarks. In addition, the nanorods exhibited rapid environmental remediation capabilities, achieving the pseudo-first order degradation of 4-nitrophenol in 75 s and methylene blue within 25 min. This improved catalytic performance may be attributed to the synergistic electronic coupling between Ni and B species, which lowers the activation energy and enhances structural stability. By harnessing the 1D nanorod framework's, morphological advantages, this work offers a scalable and robust solution for integrated energy conversion and pollutant mitigation. • Bifunctional nickel boate nanorods were synthesized using a solid sate reduction method. • Nickel boate nanorods exhibit superior H 2 production via sodium borohydride hydrolysis. • Catalysts efficiently reduce 4-nitrophenol and methylene blue pollutant. • The nanorods exhibit excellent catalytic stability and reusability over multiple cycles. • Nickel boate nanorods are cost-effective catalyst for green energy and environmental remediation applications.

International Journal of Hydrogen EnergyVol. 219
Universidad San Pablo CEU (ES), Universiti Sains Malaysia (MY), Indian Institute of Technology Delhi (IN)
Openalex Percentile: Top 49%
Nanomaterials for catalytic reactions
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